LEMEUNE Alla

• Grade/Status : Chargée de Recherche
• Institution : ENS de Lyon
• Building : M6
• Office : M6.129
• Phone : +334.72.72.80.56
  
• Fax : +334.72.72.88.60
• E-mail : Alla.Lemeune
• URL : https://www.ens-lyon.fr/CHIMIE/https://perso.ens-lyon.fr/alla.lemeune
• Axe : Matériaux Fonctionnels et Photonique (MFP)

• CAREER

  

  Alla Lemeune (Bessmertnykh-Lemeune) is CNRS Senior Researcher (CR-HC) at the Laboratoire de Chimie de l'ENS de Lyon. She graduated from Lomonosov Moscow State University in 1985. After PhD thesis with Pr. Yu. S. Shabarov in Moscow (1988), she joined the laboratory of Pr. I. P. Beletskaya at Lomonosov Moscow State University. In 2000, she moved in France and after post-doctoral fellowships with Pr. R. Guilard, Dr. G. Bertrand and Pr. F. Hénin, she was appointed Development responsible at Finorga/Novasep. She received her habilitation in Organic Chemistry in 2002 and got a tenure position at CNRS in 2005. Until 2019, she worked in the Institut de Chimie Moléculaire de l'Université de Bourgogne (Dijon) where she was director of International Associated Laboratory "LAboratory of Macrocyclic systems and RElated Materials" (LAMREM) created by CNRS, Burgundy University, Russian Academy of Sciences and Russian Foundation for Basic Researches. In 2019, she moved in Lyon to work in the group of Pr. L. Bonneviot.

  Orcid : 0000-0001-6707-6868

  Research

  

    The studies are related to sustainable chemistry and protection of the environment. They are focused on the chemistry of nitrogen-donating ligands and their complexes and consist of three main topics:

  • - development of chemosensors and sensing materials for selective detection of harmful enviromentally and bilogically relevant metal ions;

  • - biomimetic studies of supramolecular metal complexes and coordination polymers, aiming at a deeper comprehension of natural processes and development of advanced  photoactive and thermochromic materials;

  • - preparation of porous organic-inorganic materials for sustainable catalytic reactions.

  Our "bottom up" strategy is composed of three consecutive steps: 1) synthesis of sophisticated nitrogen-donating ligands functionalized by phosphorous and carboxylate groups; 2) investigation of their coordination properties; 3) design and preparation of functional organic-inorganic materials.

  We are developping rational synthetic approaches to functional nitrogen-donating nigands, studing their unusual coordination properties and exploiring different routes for their immobilization such as self-assembly, incorporation into crystalline metal-organic frameworks and amorphouse metal oxide matrices, grafting onto a surface of metal oxides and preparation of film materials using SAM and LB techniques.

  During least nine years (2011-2019), we was working with six Russian groups (Pr. V. Arslanov, Dr. A. Averin, Pr. I. Beletskaya, Dr. A. Cheprakov, Dr. Yu. gorbunova, Pr. S. Nefedov) in the frame of International Associated Laboratory of CNRS "LAboratory of Macrocyclic systems and RElated Materials" (LAMREM).

  Abilities

  

  Organic chemistry, detection and molecular materials: chemistry of small ring compounds, synthesis of macrocyclic ligands, transition metal-catalyzed reactions, chemosensors and molecular materials for detection, molecular recognitions, self-assembly, sol-gel processes, functionalization of surfaces, hybrid materials based on metal phosphonates, heterogenized catalysts.

  Publications

  

  108 publications (5 chapters in books, 3 reviews, 100 articles), 2 patents.

  2017-2023

  Chapitres de livre

  Abel A. S., Averin A. D., Beletskaya I. P., Bessmertnykh-Lemeune A., Transition-metal-catalyzed functionalization of 1,10-phenanthrolines and their complexes, In: Targets in Heterocyclic Systems: Chemistry and Properties, Vol. 24, eds.: Attanasi O. A., Gabriele B., Merino P., Spinelli D., Società Chimica Italiana: Rome, 2020, pp. 419-444, DOI:10.17374/targets.2021.24.419

  Publications dans des revues à comité de lecture

  76.       Enakieva Yu. Yu., Volostnykh M. V., Nefedov S. E., Kirakosyan G. A., Gorbunova Yu. G., Tsivadze A. Yu., Bessmertnykh-Lemeune A., Stern C., Guilard R., Gallium(III) and Indium(III) Complexes with meso-Monophosphorylated Porphyrins: Synthesis and Structure. The First Example of Dimers Formed by Self-assembly of mesoPporphyrinyl Phosphonic Acid Monoester, Inorg. Chem., 56 (5), 2017, 3055-3070, DOI: 10.1021/acs.inorgchem.6b03160.

  77.       Mitrofanov A., Brandès S., Herbst F., Rigolet S., Bessmertnykh-Lemeune A., Beletskaya I., Immobilization of Copper Complexes with (1,10-Phenanthrolinyl)phosphonates on Ttitania Ssupports for Sustainable Catalysis, J. Mater. Chem. A 5(24), 2017, 12216-12235, DOI: 10.1039/C7TA01195D.

  78.       Feuchter H., Ortiz G., Rousselin Y., Bessmertnykh-Lemeune A., Brandès S., Cadmium Metal–Organic Frameworks Based on Ditopic Triazamacrocyclic Linkers: Unusual Structural Features and Selective CO₂ Capture, Cryst. Growth Des., 17(7), 2017, 3665-3676, DOI: 10.1021/acs.cgd.7b00217.

  79.       Abdulaeva I. A., Birin K. P., Gorbunova Yu. G., Tsivadze A. Yu.,Bessmertnykh-Lemeune A., Guilard, R., Gorbunova Yu. G., Tsivadze A. Yu., Post-synthetic Methods for Functionalization of Imidazole-fused Porphyrins,  J. Porphyr. Phthalocyanines, 22(8), 2018, 619-631, DOI: 10.1142/S1088424618500475.

  80.       Abdulaeva I. A., Birin K. P., Sinelshchikova A. A., Grigoriev M. S., Lyssenko K. A., Gorbunova Yu. G., Tsivadze A. Yu., Bessmertnykh-Lemeune A., Imidazoporphyrins as Supramolecular Tectons: Synthesis and Selfassembling of Zinc 2-(4-pyridyl)-1H-imidazo[4,5-b]porphyrinate, CrystEngComm, 21(9), 2019, 1488-1498, DOI: 10.1039/C8CE01992D.

  81.       Mitrofanov A. Yu, Rousselin Y., Khrustalev V. N., Cheprakov A. V., Bessmertnykh-Lemeune A., Beletskaya I., Facile Synthesis and Self-assembly of Zinc (2-Diethoxyphosphorylethynyl)porphyrin, Eur. J. Inorg. Chem., (10), 2019, 1313-1328, DOI: 10.1002/ejic.201900004. Front Cover, Profile of Front Cover: 2019, 1300.

  82.       Abel A. S., Averin A. D., Cheprakov A. D., Denat F., Bessmertnykh-Lemeune A., Beletskaya I. P., Polyamino Substituted Quinolines: Synthesis and Multiple Metal (Cu(II), Hg(II) and Zn(II)) Monitoring in Aqueous Media, Org. Biomol. Chem., 17(17), 2019, 4243-4260, DOI: 10.1039/C9OB00259F. Front Cover.

  83.       Fang Y., Jiang X., Kadish K. M., Nefedov S. E., Kirakosyan G. A., Enakieva Yu. Yu., Gorbunova Yu. G., Tsivadze A. Yu., Stern C., Bessmertnykh-Lemeune A., Guilard R., Electrochemical, Spectroelectrochemical and Structural Studies of Mono- and Di-Phosphorylated Zinc Porphyrins and Their Self-assemblies, Inorg. Chem., 58 (7), 2019, 4665–4678, DOI: 10.1021/acs.inorgchem.9b00268.

  84.       Nefedov S. E., Birin K. P., Bessmertnykh-Lemeune A., Enakieva Yu. Yu., Sinelshchikova A. A., Gorbunova Yu. G., Tsivadze A. Yu., Stern C., Fang Y., Kadish K. M., Coordination Self-assembly through Weak Interactions in meso-Dialkoxyphosphoryl-substituted Zinc Porphyrinates, Dalton Trans., 48(16), 2019, 5372-5383, DOI:10.1039/C9DT00706G.

  85.       Ermakova E. V., Enakieva Yu. Yu., Nefedov S. E., Arslanov V. V., Gorbunova Yu. G., Tsivadze A. Yu., Stern C., Bessmertnykh-Lemeune A., Synthesis of (trans-A2)BC-Type Porphyrins with Acceptor Diethoxyphosphoryl and Various Donor Groups and their Assembling in the Solid State and at Interfaces, Eur. J. Org. Chem., (20), 2019, 3146-3162, DOI: 10.1002/ejoc.201900448.

  86.       Abel A. S., Zenkov I. S., Averin A. D., Cheprakov A. V., Bessmertnykh-Lemeune A., Orlinson B. S., Beletskaya I. P., Tuning of Emissive Properties of Ru (II) Complexes with Amino-1,10-phenanthrolines by Varying the Position of the Amino group in the Heterocycle, ChemPlusChem, 84(5), 2019, 498-503, DOI: 10.1002/cplu.201900206.

  87.       Volostnykh M. V., Borisov S. M., Konovalov M. A., Sinelshchikova A. A., Gorbunova Yu. G., Tsivadze A. Yu., Meyer M., Stern C., Bessmertnykh-Lemeune A., Platinum(II) and Palladium(II) Complexes with Electron-deficient meso-Diethoxy-phosphorylporphyrins: Synthesis, Structure and Tuning of Photophysical Properties by Varying Peripheral Substituents, Dalton Trans., 48(24), 2019, 8882-8898, DOI: 10.1039/C9DT01577A.

  88.       Abel A. S., Mitrofanov A. Yu., Yakushev A. A., Zenkov I. S., Morozkov G. V., Averin A. D., Beletskaya I. P., Michalak J., Brandes S., Bessmertnykh-Lemeune A., 1,10-Phenanthroline Carboxylic Acids for Preparation of Functionalized Metal-Organic Frameworks, Asian J. Org. Chem. 8(11), 2019, 2128-2142, DOI: 10.1002/ajoc.201900569.

  89.       Averin A. D., Abel A. S., O. K. Grigorova, Latyshev G. V., Kotovshchikov Y. N., Mitrofanov A. Y., Bessmertnykh-Lemeune A., Beletskaya I. P., Recent achievements in copper catalysis for C–N bond formation, Pure Appl. Chem., 92(8), 2020, 1181-1199, DOI:10.1515/pac-2020-0301.

  90.       Kechiche A., Fradi T., Noureddine O., Guergueb M., Loiseau F., Guerineau V., Issoui N., Lemeune A., Nasri H., Synthesis, Characterization and Catalytic Studies of Chromium(III) Porphyrin Complex with Axial Cyanate Ligands, J. Mol. Struct., 1250, Part 1, 2021, 131801, DOI: 10.1016/j.molstruc.2021.131801.

  91.       Zenkov I. S., Yakushev A. A., Abel A. S., Averin A. D., Bessmertnykh-Lemeune, A., Beletskaya, I. P., Photocatalytic Activity of Ruthenium(II) Complex with 1,10-Phenanthroline-3,8-dicarboxylic Acid in Aerobic Oxidation Reactions, Russ. J. Org. Chem., 57(9), 2021, 1398-1404, DOI: 10.1134/S1070428021090025.

  92.       Kim Y.-S., Kriegel S., Bessmertnykh-Lemeune A., Harris K. D., Limoges B., Balland V., Interplay Between Charge Accumulation and Oxygen Reduction Catalysis in Nanostructured TiO₂ Electrodes Functionalized with a Molecular Catalyst, ChemElectroChem, 8(14), 2021, 2640-2648, DOI: 10.1002/celc.202100424.

  93.       Ermakova E. V., Koroleva E. O., Shokurov A. V., Arslanov V. V., Bessmertnykh-Lemeune A., Ultra-thin Film Sensors Based on Porphyrin-5-ylphosphonate Diesters for Selective and Sensitive Dual-channel Optical Detection of Mercury(II) Ions, Dyes Pigm., 186, 2021, 108967, DOI: 10.1016/j.dyepig.2020.108967.

  94.       Yakushev A. A., Abel A. S., Averin A. D., Beletskaya I. P., Cheprakov A. V., Ziankou I. S., Bonneviot L., Bessmertnykh-Lemeune A., Visible Light Photocatalysis Promoted by Solid- and Liquid-phase Immobilized Transition Metal Complexes in Organic Synthesis, Coord. Chem. Rev., 458, 2022, 214331, DOI: 10.1016/j.ccr.2021.214331.

  95.       Abel A. S., Averin A. D., Cheprakov A. V., Beletskaya I. P., Meyer M., Bessmertnykh-Lemeune A., Ruthenium(II) Complexes with (3-Polyamino)phenanthrolines: Synthesis and Application in Sensing of Cu(II) Ions, Chemosensors, 10(2), 2022, 79, DOI: 10.3390/chemosensors10020079. The article is free of publishing charges.

  96.       Morozkov G. V., Abel A. S., Filatov M.A., Nefedov S. E., Roznyatovsky V. A., Cheprakov A. V., Mitrofanov A. Yu., Ziankou I. S., Averin A. D., Beletskaya I. P., Michalak J., Bucher C., Bonneviot L., Bessmertnykh-Lemeune A., Ruthenium(II) Complexes with Pphosphonate-substituted Phenanthroline Ligands: Synthesis, Characterization and Use in Organic Photocatalysis, Dalton Trans., 2022, 51, 13612-13630, DOI: 10.1039/D2DT01364A.

  97.       Ermakova E. V., Cheprakov A. V., Bessmertnykh-Lemeune A., Aminoquinoxaline-Based Dual Colorimetric and Fluorescent Sensors for pH Measurement in Aqueous Media, Chemosensors, 10(8), 2022, 342, DOI: 10.3390/chemosensors10080342. The article is free of publishing charges.

  98.       Ermakova E. V., Shokurov A. V., Menon C., Michalak J., Bessmertnykh-Lemeune A., Tsivadze A. Yu., Arslanov V. V., Emerging Sspecific Selectivity towards Mercury(II) Cations in Water through Supramolecular Assembly at Interfaces, Dyes Pigm., 206, 2022, 110581, DOI: 10.1016/j.dyepig.2022.110581.

  99. Abel A. S., Cheprakov A. V., Averin A. D., Beletskaya I. P., Meyer M., Brandès S., Heydel M, Bessmertnykh-Lemeune A., Rigolet S., Molecular Engineering of Ruthenium(II) Complexes with (3-Polyamino)phenanthroline Ligands for Developing Reusable Optical Sensors for Cu(II) Ions, J. Mater. Chem. C 10, 2022, 17266-17280, DOI: 10.1039/D2TC03764E.

  100. Shukaev A. V., Ermakova E. V., Fang Y., Kadish K. M., Nefedov S. E., Tafeenko V. A., Michalak J., Bessmertnykh-Lemeune A., Synthesis and Self-assembly of β-Octa[(4-diethoxyphosphoryl)phenyl]porphyrins, Inorg. Chem. 62(8), 2023, 3431-3444, DOI: 10.1021/acs.inorgchem.2c03466.

  101. Abdulaeva I. A., Birin K. P., Chassagnon R., Bessmertnykh-Lemeune A., Hybrid Materials Based on Imidazo[4,5-b]porphyrins for Catalytic Oxidation of Sulfides, Catalysts 13(2), 2023, 402, DOI:10.3390/catal13020402. The article is free of publishing charges.

  102. Ermakova E. V., Bol'shakova A. V., Bessmertnykh-Lemeune A., Dual-responsive and Reusable Optical Sensors Based on 2,3-Diaminoquinoxalines forAacidity Measurements in Low-pH Aqueous Solutions, Sensors, 23(6), 2023, 2978, DOI: 10.3390/s23062978. The article is free of publishing charges.

  103. Ermakova E., Bessmertnykh-Lemeune A. Mg and Zn Complexes with Phosphonate Substituted β-Octaphenylporphyrin as Photocatalysts for Oxidation of Sulfides, Macroheterocycles, 16(2), 2023, 117-122, DOI:10.6060/mhc235119l. This issue is dedicated to the anniversary of Prof. I. P. Beletskaya.