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Agenda de l'ENS de Lyon

BUREMA - Inelastic Electron Tunneling Spectroscopy with the Scanning Tunneling Microscope : A combined theory-experiment approach

Soutenance de thèse

Lundi 01 juil 2013
14h30
Soutenance de Mme Shiri BUREMA du laboratoire de Chimie de Lyon sous la direction de Mme Marie-Laure BOCQUET.

Intervenant(s)

Soutenance de Mme Shiri BUREMA du laboratoire de Chimie de Lyon sous la direction de Mme Marie-Laure BOCQUET.

Description générale

Résumé de la thèse

 Inelastic Electron Tunneling Spectroscopy (IETS) with the Scanning Tunneling Microscope (STM) is a novel vibrational spectroscopy technique that permits to characterize very subtle properties of molecules adsorbed on metallic surfaces. Its proposed symmetry-based propensity selection rules, however, fail to fully capture its exact mechanism and influencing factors; are not directly retraceable to an adsorbate property and are cumbersome. In this thesis, a theoretical approach was taken to improve them. An IETS simulation protocol has been developed, parameterized and benchmarked, and consequently used to calculate IETS spectra for a set of systematically related small molecules on copper surfaces. Extending IETS principles were deduced that refer to the tunneling state’s vacuum extension, the selective activating/quenching of certain types of modes due to the moieties’ electronic properties, and the applicability of a sum rule of IETS signals. Also, fingerprinting IETS-signals that enable discrimination between adsorbate orientations, the chemical nature of atoms and structural isomers were determined and a strategy using straightforward electronic density distribution properties of the isolated molecule to predict IETS activity without (large) computational cost was developed. This expertise was used to rationalize and interpret experimentally measured IETS spectra for adsorbed metalloporphyrins and metallophthalocyanines, being the first IETS studies of this large size. This experimental approach permitted to determine the current limitations of IETS-simulations. The associated identification shortcomings were resolved by conducting complementary STM-image simulations.

Complément

Salle des Thèses - Site Monod - ENS Lyon